Investigating the microstructure and mechanical properties of metakaolin-based polypropylene fiber-reinforced geopolymer concrete using different monomer ratios

Document Type : Original Article

Authors

Department of Civil engineering and Applied sciences, Queens University, Kingston, Canada.

Abstract

Researchers have focused on the fabrication and implementation of concrete that has optimal characteristics, logical price with minimum harmful impacts on the environment. For this purpose, the current project was conducted. Geopolymer cement, due to its high durability, insignificant energy consumption, least CO2 emissions, acceptable investment cost, and specific characteristics, is accounted as a new class of mineral binders which is different from such binders as Portland cement. In this research, the geopolymer concrete was made using metakaolin precursor containing 0.3, 0.5, and 1% polypropylene fibers together with monomer with 2, 2.5, and 3 ratios. Next, a number of engineering properties such as the bending strength, compressive strength, electrical resistivity, water absorption, and microstructure were assessed at 90 days age using the electron microscopy scanning method.

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Main Subjects


[1] Esparham A, Moradikhou AB, Jamshidi Avanaki M. Effect of Various Alkaline Activator Solutions on Compressive Strength of Fly Ash-Based Geopolymer Concrete. Journal of civil Engineering and Materials Application. 2020 Jun 1;4(2):115-23. [View at Google Scholar]; [View at Publisher].
[2] Mahboubi B, Guo Z, Wu H. Evaluation of durability behavior of geopolymer concrete containing Nano-silica and Nano-clay additives in acidic media. Journal of civil Engineering and Materials Application. 2019 Sep 1;3(3):163-71. [View at Google Scholar]; [View at Publisher].
[3] Sekhavati P, Jafarkazemi M, Kaya Ö. Investigating Durability Behavior and Compressive Strength of Lightweight Concrete Containing the Nano-Silica and Nano Lime Additives In the Acid Environment. Journal of civil Engineering and Materials Application. 2019 Jun 1;3(2):109-17. [View at Google Scholar]; [View at Publisher].
[4] Mousavi Davoudi SA, Khalilpasha MH. A Study on the Structural Effects of Bagasse Sugar Cane Stem In Structural Concrete Mixture in Sulfate and Chloride Environments. Concrete Research. 2020 Sep 22;13(3):137-49. [View at Google Scholar]; [View at Publisher].
[5] Mehrinejad Khotbehsara M, Mohseni E, Ozbakkaloglu T, Ranjbar MM. Retracted: Durability Characteristics of Self-Compacting Concrete Incorporating Pumice and Metakaolin. Journal of materials in civil engineering. 2017 Nov 1;29(11):04017218. [View at Google Scholar]; [View at Publisher].
[6] Davidovits, J. (1999) “Chemistry of geopolymeric systems, terminology” In Proceedings Second International Conference, Geopolymer ’99,Davidovits, J., Davidovits, R. and James, C. (Eds.),Geopolymer Institute, Saint-Quentin: France, pp. 9-39. [View at Google Scholar].
[7] Barbosa VF, MacKenzie KJ, Thaumaturgo C. Synthesis and characterisation of materials based on inorganic polymers of alumina and silica: sodium polysialate polymers. International journal of inorganic materials. 2000 Sep 1;2(4):309-17. [View at Google Scholar]; [View at Publisher].
[8] Teixeira-Pinto, A., Fernandes, P. and Jalali, S. (2002). Geopolymer Manufacture and Application-Main problems When Using Concrete Technology. Geopolymers 2002 International Conference, Melbourne, Australia, Siloxo Pty. Ltd. [View at Google Scholar]; [View at Publisher].
[9] Palomo A, Grutzeck MW, Blanco MT. Alkali-activated fly ashes: A cement for the future. Cement and concrete research. 1999 Aug 1;29(8):1323-9. [View at Google Scholar]; [View at Publisher].
[10] Swanepoel JC, Strydom CA. Utilisation of fly ash in a geopolymeric material. Applied geochemistry. 2002 Aug 1;17(8):1143-8. [View at Google Scholar]; [View at Publisher].
[11] Xu H, Van Deventer JS. Ab initio calculations on the five-membered alumino-silicate framework rings model: implications for dissolution in alkaline solutions. Computers & chemistry. 2000 May 1;24(3-4):391-404. [View at Google Scholar]; [View at Publisher].
[12] Saraya ME, El-Fadaly E. Preliminary study of alkali activation of basalt: effect of NaOH concentration on geopolymerization of basalt. Journal of Materials Science and Chemical Engineering. 2017 Nov 10;5(11):58-76. [View at Google Scholar]; [View at Publisher].
[13] Davidovits J. Properties of geopolymer cements. InFirst international conference on alkaline cements and concretes 1994 Oct 11 (Vol. 1, pp. 131-149). Kiev State Technical University, Ukraine: Scientific Research Institute on Binders and Materials. [View at Google Scholar]; [View at Publisher].
[14] Ghanei A, Jafari F, Khotbehsara MM, Mohseni E, Tang W, Cui H. Effect of nano-CuO on engineering and microstructure properties of fibre-reinforced mortars incorporating metakaolin: Experimental and numerical studies. Materials. 2017 Oct;10(10):1215. [View at Google Scholar]; [View at Publisher].
[15] Noushini A, Castel A, Aldred J, Rawal A. Chloride diffusion resistance and chloride binding capacity of fly ash-based geopolymer concrete. Cement and Concrete Composites. 2020 Jan 1;105:103290. [View at Google Scholar]; [View at Publisher].
[16] Van Dao D, Trinh SH. Mechanical properties of fly ash based geopolymer concrete using only steel slag as aggregate. InCIGOS 2019, Innovation for Sustainable Infrastructure 2020 (pp. 415-420). Springer, Singapore. [View at Google Scholar]; [View at Publisher].
[17] Sandanayake M, Gunasekara C, Law D, Zhang G, Setunge S, Wanijuru D. Sustainable criterion selection framework for green building materials–an optimisation based study of fly-ash Geopolymer concrete. Sustainable Materials and Technologies. 2020 Sep 1;25:e00178. [View at Google Scholar]; [View at Publisher].
[18] Bernal SA, Rodríguez ED, de Gutiérrez RM, Gordillo M, Provis JL. Mechanical and thermal characterisation of geopolymers based on silicate-activated metakaolin/slag blends. Journal of materials science. 2011 Aug;46(16):5477-86. [View at Google Scholar]; [View at Publisher].
[19] Deb PS, Nath P, Sarker PK. The effects of ground granulated blast-furnace slag blending with fly ash and activator content on the workability and strength properties of geopolymer concrete cured at ambient temperature. Materials & Design (1980-2015). 2014 Oct 1;62:32-9. [View at Google Scholar]; [View at Publisher].
[20] Yip CK, Van Deventer JS. Microanalysis of calcium silicate hydrate gel formed within a geopolymeric binder. Journal of Materials Science. 2003 Sep;38(18):3851-60. [View at Google Scholar]; [View at Publisher].
[21] Temuujin JV, Van Riessen A, Williams R. Influence of calcium compounds on the mechanical properties of fly ash geopolymer pastes. Journal of hazardous materials. 2009 Aug 15;167(1-3):82-8. [View at Google Scholar]; [View at Publisher].
[22] Aliabdo AA, Abd Elmoaty M, Salem HA. Effect of water addition, plasticizer and alkaline solution constitution on fly ash based geopolymer concrete performance. Construction and Building Materials. 2016 Sep 15;121:694-703. [View at Google Scholar]; [View at Publisher].
[23] Singh B, Rahman MR, Paswan R, Bhattacharyya SK. Effect of activator concentration on the strength, ITZ and drying shrinkage of fly ash/slag geopolymer concrete. Construction and Building Materials. 2016 Aug 15;118:171-9. [View at Google Scholar]; [View at Publisher].
[24] Song PS, Hwang S, Sheu BC. Strength properties of nylon-and polypropylene-fiber-reinforced concretes. Cement and Concrete Research. 2005 Aug 1;35(8):1546-50. [View at Google Scholar]; [View at Publisher].
[25] Madandoust R, Mohseni E, Mousavi SY, Namnevis M. An experimental investigation on the durability of self-compacting mortar containing nano-SiO2, nano-Fe2O3 and nano-CuO. Construction and Building Materials. 2015 Jul 1;86:44-50. [View at Google Scholar]; [View at Publisher].