Geopolymer Concrete Based on Class C Fly ash Cured at Ambient Condition

Document Type : Original Article

Authors

1 Department of Chemical Engineering, Central Tehran Branch, Islamic Azad University, Tehran, Iran.

2 Department of Civil Engineering, Science and Research Branch, Islamic Azad University, Tehran, Iran.

Abstract

In recent years, geopolymers, as a new class of green cement binders, have been considered as an environmental-friendly alternative to Ordinary Portland Cement (OPC), which can potentially reduce the negative environmental impacts of OPC. Geopolymers are inorganic alumina-silicate materials produced from raw materials in combination with an alkaline activator solution. The alkaline activator solution is one of the pillars of the geopolymerization process, playing an important role in the formation of crystalline structures of Si and Al. Therefore, it seems necessary to study the impact of various alkaline activator solutions on the mechanical strength of Geopolymer Concrete (GPC). On the other hand, in most previous research in this regard, GPC based on Class F fly ash and high-temperature curing condition have been studied. Hence, in this research, Class C fly ash, and ambient curing conditions were used to make GPC. The obtained results indicated that in ambient curing conditions, using sodium hydroxide and sodium silicate results in higher compressive strength and lower permeability compared to potassium-based (potassium hydroxide and potassium silicate) and a combination of sodium potassium-based alkaline activator solutions. But, at elevated curing temperatures, a potassium-based activator provided higher compressive strength. Moreover, simultaneous inclusion of NaOH and KOH led to a decline the compressive strength. Furthermore, the obtained results indicated that increasing the NaOH and KOH concentration resulted in higher compressive strength. The optimal SiO2/Na2O ratio was 2 in the case of using 14M NaOH solution and 2.5 in the case of using 10M NaOH solution.

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[1] Moradikhou AB, Esparham A, Avanaki MJ. Physical & mechanical properties of fiber reinforced metakaolin-based geopolymer concrete. Construction and Building Materials. 2020 Aug 10;251:118965. [View at Google Scholar]; [View at Publisher].
[2] Esparham A, Moradikhou AB, Andalib FK, Avanaki MJ. Strength characteristics of granulated ground blast furnace slag-based geopolymer concrete. Advances in concrete construction. 2021;11(3):219-29. [View at Google Scholar]; [View at Publisher].
[3] Moradikhou AB, Esparham A. Water Absorption, Density, Mechanical Strengths and High-temperature Resistance of Metakaolin-based Geopolymer Concrete Reinforced with Hybrid Polyolefin and Simple Polypropylene Fibers. Advance Researches in Civil Engineering.;3(2):1-5. [View at Google Scholar]; [View at Publisher].
[4] Rashad AM. A comprehensive overview about the influence of different additives on the properties of alkali-activated slag–A guide for Civil Engineer. Construction and building materials. 2013 Oct 1;47:29-55. [View at Google Scholar]; [View at Publisher].
[5] Moradikhou AB, Ravanshadnia M. Evaluation of CO2 Emissions Reduction Strategies in the Iranian Cement Industry. Journal of Civil Engineering and Materials Application. 2021 Sep 1;5(3):107-14. [View at Google Scholar]; [View at Publisher].
[6] De Silva P, Sagoe-Crenstil K, Sirivivatnanon V. Kinetics of geopolymerization: role of Al2O3 and SiO2. Cement and Concrete Research. 2007 Apr 1;37(4):512-8. [View at Google Scholar]; [View at Publisher].
 [7] Neupane K, Chalmers D, Kidd P. High-strength geopolymer concrete-properties, advantages and challenges. Advances in Materials. 2018 Jun 25;7(2):15-25. [View at Google Scholar]; [View at Publisher].
[8] Görhan G, Kürklü G. The influence of the NaOH solution on the properties of the fly ash-based geopolymer mortar cured at different temperatures. Composites part b: engineering. 2014 Mar 1;58:371-7. [View at Google Scholar]; [View at Publisher].
[9] Gao K, Lin KL, Wang D, Hwang CL, Tuan BL, Shiu HS, Cheng TW. Effect of nano-SiO2 on the alkali-activated characteristics of metakaolin-based geopolymers. Construction and building materials. 2013 Nov 1;48:441-7. [View at Google Scholar]; [View at Publisher].
[10] Moradikhou AB, Safehian M. Comparison of Mechanical Strengths and Resistance to Acidic Conditions, Permeability and Resistance to Elevated Temperatures of Geopolymer Concrete and Conventional Concrete. Advance Researches in Civil Engineering. 2021 Jun 1;3(2):27-37. [View at Google Scholar]; [View at Publisher].
[11] Moradikhou AB, Safehian M. Comparison of Mechanical Strengths and Resistance to Acidic Conditions, Permeability and Resistance to Elevated Temperatures of Geopolymer Concrete and Conventional Concrete. Advance Researches in Civil Engineering. 2021 Jun 1;3(2):27-37. [View at Google Scholar]; [View at Publisher].
[12] Karthik A, Sudalaimani K, Kumar CV. Investigation on mechanical properties of fly ash-ground granulated blast furnace slag based self curing bio-geopolymer concrete. Construction and Building Materials. 2017 Sep 15;149:338-49. [View at Google Scholar]; [View at Publisher].
[13] Yaseri S, Hajiaghaei G, Mohammadi F, Mahdikhani M, Farokhzad R. The role of synthesis parameters on the workability, setting and strength properties of binary binder based geopolymer paste. Construction and Building Materials. 2017 Dec 30;157:534-45. [View at Google Scholar]; [View at Publisher].
[14] Cheng TW, Chiu JP. Fire-resistant geopolymer produced by granulated blast furnace slag. Minerals engineering. 2003 Mar 1;16(3):205-10. [View at Google Scholar]; [View at Publisher].
[15] Sarker PK, Kelly S, Yao Z. Effect of fire exposure on cracking, spalling and residual strength of fly ash geopolymer concrete. Materials & Design. 2014 Nov 1;63:584-92. [View at Google Scholar]; [View at Publisher].
[16] Sakkas K, Panias D, Nomikos PP, Sofianos AI. Potassium based geopolymer for passive fire protection of concrete tunnels linings. Tunnelling and underground space technology. 2014 Jul 1;43:148-56. [View at Google Scholar]; [View at Publisher].
[17] Lee WK, Van Deventer JS. The effects of inorganic salt contamination on the strength and durability of geopolymers. Colloids and Surfaces A: Physicochemical and Engineering Aspects. 2002 Dec 3;211(2-3):115-26. [View at Google Scholar]; [View at Publisher].
[18] Palomo A, Blanco-Varela MT, Granizo ML, Puertas F, Vazquez T, Grutzeck MW. Chemical stability of cementitious materials based on metakaolin. Cement and Concrete research. 1999 Jul 1;29(7):997-1004. [View at Google Scholar]; [View at Publisher].
[19] Zhang M, Guo H, El-Korchi T, Zhang G, Tao M. Experimental feasibility study of geopolymer as the next-generation soil stabilizer. Construction and building materials. 2013 Oct 1;47:1468-78. [View at Google Scholar]; [View at Publisher].
[20] Hosseini MH, Mousavi Kashi A, Emami F, Esparham A. Effect of Simple and Hybrid Polymer Fibers on Mechanical Strengths and High-temperature Resistance of Metakaolin-based Geopolymer Concrete. Modares Civil Engineering journal. 2020 May 10;20(2):147-61. [View at Google Scholar]; [View at Publisher].
[21] Esparham A, Moradikhou AB. A Novel Type of Alkaline Activator for Geopolymer Concrete Based on Class C Fly Ash. Advance Researches in Civil Engineering. 2021;3(1):1-3. [View at Google Scholar]; [View at Publisher].
[22] Esparham A. Factors Influencing Compressive Strength of Metakaolin-based Geopolymer Concrete. Modares Civil Engineering journal. 2020 Apr 10;20(1):53-66. [View at Google Scholar]; [View at Publisher].
[23] Davidovits J. Geopolymers of the first generation: SILIFACE-Process. InGeopolymer 1988 Jun (Vol. 88, No. 1, pp. 49-67). [View at Google Scholar]; [View at Publisher].
[24] Davidovits J. Geopolymers: inorganic polymeric new materials. Journal of Thermal Analysis and calorimetry. 1991 Aug 1;37(8):1633-56. [View at Google Scholar]; [View at Publisher].
[25] Patel YJ, Shah N. Development of self-compacting geopolymer concrete as a sustainable construction material. Sustainable Environment Research. 2018 Nov 1;28(6):412-21. [View at Google Scholar]; [View at Publisher].
[26] Hardjito D, Wallah SE, Sumajouw DM, Rangan BV. Factors influencing the compressive strength of fly ash-based geopolymer concrete. civil engineering dimension. 2004 Sep 15;6(2):88-93. [View at Google Scholar]; [View at Publisher].
[27] ASTM C618-19, Standard Specification for Coal Fly Ash and Raw or Calcined Natural Pozzolan for Use in Concrete, ASTM International, West Conshohocken, PA, 2019. [View at Publisher].
[28] ASTM C33 / C33M-18, Standard Specification for Concrete Aggregates, ASTM International, West Conshohocken, PA, 2018. [View at Publisher].
[29] ASTM C127-15, Standard Test Method for Relative Density (Specific Gravity) and Absorption of Coarse Aggregate, ASTM International, West Conshohocken, PA, 2015. [View at Publisher].
[30] ASTM C128-15, Standard Test Method for Relative Density (Specific Gravity) and Absorption of Fine Aggregate, ASTM International, West Conshohocken, PA, 2015. [View at Publisher].
[31] ASTM C136 / C136M-14, Standard Test Method for Sieve Analysis of Fine and Coarse Aggregates, ASTM International, West Conshohocken, PA, 2014. [View at Publisher].
[32] ASTM D2419-14, Standard Test Method for Sand Equivalent Value of Soils and Fine Aggregate, ASTM International, West Conshohocken, PA, 2014. [View at Publisher].
[33] D. Hardjito, B.V. Rangan, Development and properties of low-calcium fly ash-based geopolymer concrete, Faculty of Engineering Curtin University of Technology, Perth, Australia, 2005. [View at Google Scholar]; [View at Publisher].
[34] British Standards Institution, 1983, Testing Concrete: Method for Determination of the Compressive Strength of Concrete Cubes, BS1881: Part116: 1983, London. [View at Publisher].
[35] ASTM C642-13, Standard Test Method for Density, Absorption, and Voids in Hardened Concrete, ASTM International, West Conshohocken, PA, 2013. [View at Publisher].
[36] Davidovits J. Geopolymers and geopolymeric materials. Journal of thermal analysis. 1989 Mar;35(2):429-41. [View at Google Scholar]; [View at Publisher].
[37] Duxson P, Provis JL, Lukey GC, Van Deventer JS. The role of inorganic polymer technology in the development of ‘green concrete’. cement and concrete research. 2007 Dec 1;37(12):1590-7. [View at Google Scholar]; [View at Publisher].
[38] Komnitsas K, Zaharaki D, Perdikatsis V. Effect of synthesis parameters on the compressive strength of low-calcium ferronickel slag inorganic polymers. Journal of Hazardous Materials. 2009 Jan 30;161(2-3):760-8. [View at Google Scholar]; [View at Publisher].
[39] Xu H, Van Deventer JS. The geopolymerisation of alumino-silicate minerals. International journal of mineral processing. 2000 Jun 1;59(3):247-66. [View at Google Scholar]; [View at Publisher].
[40] Panagiotopoulou C, Kakali G, Tsivilis S, Perraki T, Perraki M. Synthesis and characterisation of slag based geopolymers. InMaterials science forum 2010 (Vol. 636, pp. 155-160). Trans Tech Publications Ltd. [View at Google Scholar]; [View at Publisher].
[41] Van Jaarsveld JG, Van Deventer JS, Lukey GC. The characterisation of source materials in fly ash-based geopolymers. Materials Letters. 2003 Jan 1;57(7):1272-80. [View at Google Scholar]; [View at Publisher].
[42] Patel YJ, Shah N. Study on workability and hardened properties of self compacted geopolymer concrete cured at ambient temperature. Indian Journal of Science and Technology. 2018 Jan 1;11(1):1-2. [View at Google Scholar]; [View at Publisher].
[43] Petrus HT, Hulu JO, Dalton GS, Malinda EL, Prakosa RA. Effect of bentonite addition on geopolymer concrete from geothermal silica. InMaterials Science Forum 2016 (Vol. 841, pp. 7-15). Trans Tech Publications Ltd. [View at Google Scholar]; [View at Publisher].
[44] Gebregziabiher BS, Thomas RJ, Peethamparan S. Temperature and activator effect on early-age reaction kinetics of alkali-activated slag binders. Construction and Building Materials. 2016 Jun 15;113:783-93. [View at Google Scholar]; [View at Publisher].
[45] Muhammad N, Baharom S, Amirah N, Ghazali M, Alias NA. Effect of heat curing temperatures on fly ash-based geopolymer concrete. Int. J. Eng. Technol. 2019 Jan;8(1.2):15. [View at Google Scholar]; [View at Publisher].
[46] Memon FA, Nuruddin MF, Demie S, Shafiq N. Effect of curing conditions on strength of fly ash-based self-compacting geopolymer concrete. International Journal of Civil and Environmental Engineering. 2011 Aug 22;5(8):342-5. [View at Google Scholar]; [View at Publisher].